CHEMISTRY OF MATERIALS
VOL. 11 , NO. 6 , 1999
CONTENTS BY TOPIC
Bio- (and Biomimetic) Atomic Force Microscopic Studies of Site-Directed Immobilization of Antibodies Using Their
Materials Carbohydrate Residues W. Qian et al. 1399
CatalytioMaterials Identification and Stability of the Nitrogenous species in Zirconium Phosphate Oxymtride
Catalysts Nathalie Fripiat et aL 1434
Assembly of Mesoporous Silica Molecular Sieves Based on Noniunic Ethoxylated Sorbitan Esters
as Structure Directors Eric Prouzet et aL 1498
Alumination and Ion Exchange ofMesoporous SBA-15 Molecular Sieves
Zhaohua Luan et al. 1621
Clusters and Colloids Successive Use ofAmphiphilic Block Copolymers as Nanoreactors and Templates: Preparation
of Porous Silica with Metal Nanoparticles Lyudmila Bronstcin et aL 1402
Coatings ROMP-Based, Highly Hydrophilic Poly(7-oxanorborn-2-ene-5,6-dicarboxylic acid)-Coated Silica
for Analytical and Preparative Scale High-Performance Ion Chromatography 1533
Michael R. Buchmeiser et aL
Electronic Materials Solid-State Structures of Phenyleneethynylenes: Comparison of Monomers and Polymers 1416
Uwe H. F. Bunz et aL
Structural Effects of Cation Size Variance in Magnetoresistive Manganese Oxide Perovskites
Lide M. Rodriguez-Martinez et at. 1504
Oxygen-Modified Poly(4-dicyanomethylene-4H-cyclopenta(2,l-b;3,4-b')dithiophene): A Tunable
Low Band Gap Polymer , . . Huan Huang et aL 1541
Fluids and Liquid Vitrified Chiral-Nematic Liquid Crystalline Films for Selective Reflection and Circular Polariza-
Crystals tion Dimitris Katais et al. 1590
Inorganic Solids/ Low-Temperature Structure and Magnetic Properties of the Spinel LiMn(2)O(4) A Frustrated
Ceramics Antiferromagnet and Cathode Material . . . A. S. Wills et al. 1510
Neutron Diffraction Study of the Structures of Ba(5)Culr(3)O(120 and Ba(16)Cu(3)Ir(10)O(39)
. . . Graeme R. Blake et uL 1551
Ah Initio Structure Determination and Dehydration Dynamics of YK(C(2)O(4) )(2).4H2O Studied by
X-ray Powder Diffraction . . . Thierry Bataille et aL 1559
Structure and Phase Transition ofGdBOg . . . M. Ren et al. 1576
The Stannides LaRhSn(2)and CeRhSn(2) M.Ren et al 1597
Di(tert-butyl)phosphate Complexes of Aluminum: Precursors to Aluminum Phosphate Xerogels
and Thin FilmsClaus G. Luginair et al. 1615
Inorganic/Organic New Crystalline Frameworks Formed from l,2-Bis(4-pyridyl)ethyne and Co(NO3)(2): Interpcnctrat-
Networks ing Molecular Ladders and an Unexpected Molecular Parquet Pattern from T-Shaped Building
Blocks Yu-Bin Dong et al. 1413
Molecular Modeling and Large-Angle X-ray Scattering Studies of the Structure ofSernicrystalline
Poly[bis(phenoxy)phosphazene] . . . Ruggero Caminiti et al. 1492
Hybrid Open Networks (MIL 16): Synthesis, Crystal Structure, and Ferrimagnetism of
Co4(OH)2(H20)2(C4H404)3 2H2O, a New Layered Cobalt(II) Carboxylate with 14-Membered Ring
Channels , , . Carine Livage et al. 1546
Layered Tin(II) Oxalates Possessing Large Apertures , . . Srinivasan Natarajan et al. 1633
Layered Materials Synthesis and Spectroscopic Investigations of a Crystalline Humidity Sensor: Bis(triphenylphos-
(including phine)iminium 2,2'-Bipyridyltetracyanoruthenate , , . Jon K. Evju et al. 1425
Intercalation Electrochemical Growth and Characterization ofPolyoxometalate-Containing Monolayers and
Compounds) Multilayers on Alkanethiol Monolayers Self-Assembled on Gold Electrodes
Long Cheng et al. 1465
Dielectric Properties of the Lamellar Niobates and Titanoniobates AM(2)Nb(3)O(10) and ATiNbO(5) (A
=H, K, M= Ca, Pb), and Their Condensation Products Ca(4)Nb(6)O(19) and Ti(2)Nb(2)O(9)
. . . Mingming Fang et al. 1519
Layer-by-Layer Growth and Condensation Reactions ofNiobate and Titanoniobate Thin Films
, .. Mingming Fang et al. 1526
Construction ofNanostructured Carbonaceous Films by the Layer-by-Layer Self-Assembly of
Poly(diallyldimethylammonium) Chloride and Poly(amic acid) and Subsequent Pyrolysis
Isamu Moriguchi et al. 1603
Layered Tin(II) Oxalates Possessing Large Apertures , . , Srinivasan Natarajan et al. 1633
Magnetic Materials Structural Effects of Cation Size Variance m Magnetoresistive Manganese Oxide Perovskites
, . . Lide M. Rodrigliez-Martinez et al. 1504
Low-Temperature Structure and Magnetic Properties of the Spinel LiMn(2)C(4): A Frustrated
Antiferromagnet and Cathode Material , , . A, S. Wills et al. 1510
Hybrid Open Networks (MIL 16): Synthesis, Crystal Structure, and Ferrimagnetism of
Co4(OH)2(H20)2(C4H4O4)3.2H2O, a New Layered Cobalt(II) Carboxylate with 14-Membered Ring
Channels - - - Carine Livage et aL 1546
Processible Nanostructured Materials with Electrical Conductivity and Magnetic Susceptibility:
Preparation and Properties ofMaghemite/Polyaniline Nanocornposite Films
, . , Ben Zhong Tang et aL 1581
The Stannides LaRhSna and GeRhSna Dirk Niepmann et al. 1697
Molecular Crystals Noncovalent Polymer-like Structures of 1,1'- Bicyclohexylidene-4,4'-dioneDioxmie and 1,1'-
Bicyclohexyl-4,4'-dione Dioxime, Chiral Recognition in the Solid State
Albert W, Marsman et al. 1484
NLO Materials Side-Chain Nonlinear Optical Polymers Containing a Styrylfuran-Based Chromophore with Large
Electro-optic Properties Sangyup Song et aL 1406
Synthesis and Characterization of Nonlinear Optical Chromophores with Conformationally Locked
Polyenes Possessing Enhanced Thermal Stability . , , Yuan-Cheng Shu et aL 1628
Nanophase Materials Successive Use ofAmphiphilic Block Copolymers as Nanoreactors and Templates: Preparation
of Porous Silica with Metal Nanoparticles , - . Lyudmila Bronstein et aL 1402
Poly(borosilazane) Precursors to Ceramic Nanocomposites . - . Wayde R. Schmidt et aL 1455
Isolated Linear Alkanes in Aromatic Nanochannels - . , A- Comotti et al. 1476
Processible Nanostructurcd Materials with Electrical Conductivity and Magnetic Susceptibility:
Preparation and Properties of Maghemite/Polyaniline Nanocomposite Films
Ben Zhong Tang et al. 1581
Optical Materials Photorefractivity in Nematic Liquid Crystals Doped with a Conjugated Polymer: Mechanisms
for Enhanced Charge Transport , . , Gary P. Wiederrecht et at. 1409
Synthesis, Properties, and Application of New Luminescent Polymers with Both Hole and Electron
Injection Abilities for Light-Ennitting Devices . . , Xiao-Chang Li et aL 1568
VitriFied Chiral-Nematic Liquid Crystalline Films for Selective Reflection and Circular Polariza-
tion Dimitris Katsis et at. 1590
Phase Transitions Structure and Phase Transition of GdBOa M. Ren et aL 1576
Polymeric Materials Side-Chain Nonlinear Optical Polymers Containing a Styrylfuran-Based Chromophore with Large
Electro-optic Properties Sangyup Song et aL 1406
Photorefractivity in Nematic Liquid Crystals Doped with a Conjugated Polymer: Mechanisms
for Enhanced Charge Transport - , . Gary P. Wiederrecht et al 1409
New Crystalline Frameworks Formed from l,2-Bis(4-pyridyl)ethyne and Co(N03)2: Interpenetrat-
ing Molecular Ladders and an Unexpected Molecular Parquet Pattern from T-Shaped Building
Blocks Yu-Bin Dong et at. 1413
Solid-State Structures of Phenyleneethynylenes: Comparison of Monomers and Polymers
Uwe H. K Bunz et at. 1416
Molecular Modeling and Large-Angle X-ray Scattering Studies of the Structure of Semicrystalline
Poly(bis)(phenoxy)phosphazenej . , , Ruggero Caminiti et aL 1492
ROMP-Rased, Highly Hydrophilic Poly(7-oxanorborn-2-ene-5,6-dicarboxylic acid)-Coatcd Silica
for Analytical and Preparative Scale High-Performance Ion Chromatography
Michael It. Buchmeiser et at. 1533
Oxygon-Modified Poly(4-dicyanomethylene-4H-cyclopentar2,l-6;3,4-b']dithiophene): A Tunable
Low Band Gap Polymer . . . Huan Huang et al. 1541
Synthesis, Properties, and Application of New Luminescent Polymers with Both Hole and Electron
Injection Abilities for Light-Emitting Devices Xiao-Chang Li et aL 1568
Porous Materials Interface Charge Density Matching as Driving Force for New Mesostructured Oxovanadium
Phosphates with Hexagonal Structure, (CTA)(x)VOPO(4).zH(2)O , , , Jamal El Haskouri et al. 1446
Isolated Linear Alkanes in Aromatic Nanochannels , . . A. Comotti et al 1476
Assembly of Mesoporous Silica Molecular Sieves Based on Nonionic Ethoxylated Sorbitan Esters
as Structure Directors Eric Prouzet et al. 1498
Alignment of Mesoporous Silica on a Glass Substrate by a Rubbing Method
Hirokatsu Miyata et aL 1609
Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves
Zhaohua Luan et al. 1621
Precursor Routes to Poly(borosilazane) Precursors to Ceramic Nanocomposites Wayde R. Schmidt et al. 1455
Materials Dielectric Properties of the Lamellar Niohates and Titanoniobates AM2Nb30io and ATiNbOs (A
= H, K, M = Ca, Pb), and Their Condensation Products Ca(4)Nb(6)O(19) and Ti(2)Nb(2)O(9)
Mingming Fang et al. 1519
Ab Initio Structure Determination and Dehydration Dynamics of YK(C(2)O(4) )2.4H(2)O Studied by
X-ray Powder Diffraction - . - Thierry Bataille et aL 1559
Di(tert-butyl)phosphate Complexes of Aluminum: Precursors to Aluminum Phosphate Xerogels
and Thin Films Claus G. Lugmair et aL 1615
Self-Assembled Interface Charge Density Matching as Driving Force for New Mesostructured Oxovanadium
Materials Phosphates with Hexagonal Structure, (CTA)(x)VOPO(4).zH(2)O Jamal El Haskouri et aL 1446
Electrochemical Growth and Characterization of'Polyoxolnetalate-Containing Monolayers and
Multilayers on Alkanethiol Monolayers Self-Assembled on Gold Electrodes
. . . Long Cheng et al. 1465
Noncovalent Polymer-like Structures of l,l'-Bicycluhexylidene-4,4'-dione Dioxime and 1,1'-
Bicyclohexyl-4,4'-dione Dioxirne. Chiral Recognition in the Solid State
Albert W, Marsman et aL 1484
Sensors Synthesis and Spectroscopic Investigations of a Crystalline Humidity Sensor: Bisdriphenylphoa-
phine)imimum 2,2'-Bipyridyltetracyanoruthenate . . . Jon K. Evju et aL 1425
Surface and Interfacial Atomic Force Microscopic Studies of Site-Directed Immobilization of Antibodies Using Their
Phenomena Carbohydrate Residues .., W. Qian et aL 1399
Thin Films and Layer-by-Layer Growth and Condensation Reactions ofNiobate and Titanoniobate Thin Films
Monolayers Mingming Fang et aL 1526
Construction of Nanostructured Carbonaceous Films by the Layer-by-Layer Self-Assembly of
Poly(diallyldimethylammonium) Chloride and Poly(amic acid) and Subsequent Pyrolysis
Isamu Moriguchi et aL 1603
____________________________
CHEMISTRY OF MATERIALS
VOLUME 11, NUMBER 7, JULY 1999
hyuk Choi, Young-Uk Kwon,* and
Oc Hee Han
choem. Mater. 1999,11, 1641
Nanocomposite Gels between {V(10)O(28)}6-
and [A1O(4)Al(12)(OH)(2)4(H(2)O)12](7+) Polyoxo-
metalate Clusters
Sang Kyeong Yun and
Joachim Maier*
Chem. Mater. 1999, 11, 1644
Synthesis and Ionic Conductivity of Su-
pramolecular Layered Silicate Hybrids
ofPhosphotungstates and Poly(ethylene
glycol) Dicarboxylates
Andrew P. Purdy
Chem. Mater. 1999, 11, 1648
Ammonothermal Synthesis of Cubic Gal-
lium Nitride
Aldo J. G. Zarbin, Oswaldo L. Alves, 1652 Silver Antimonates with Pyrochlore-like Structure Prepared by Thermal
J. Manuel Amarilla, Treatment of Silver Proton-Exchanged Antimonic Acid: Formation
Rosa M. Rojas, and Jose M. Rojo* Process and Structural Characterization
Zhibo Zhang, Dmitry Gekhtman, 1659 Processing and Characterization of Single-Crystalline Ultrafine Bismuth
Mildred S. Dresselhaus, and Nanowires
Jackie Y. Ying*
Feng Bai, Liang-Chy Chien,* 1666 Synthesis and Characterization of Isoregic Chiral Smectic Polyesters
Chistopher Y. Li,
Stephen Z. D. Cheng, and
Rolfe Petschek
Plinio Innocenzi,* 1672 New Synthetic Route to (3-Glycidoxypropyl)trimethoxysilane-Based
Giovanna Brusatin, Hybrid Organic-Inorganic Materials
Massimo Guglielmi, and
Roberta Bertani
Arian R. Overweg,* Jan W. de Haan, 1680 Synthesis and Characterization of Some Heterometal-Substituted
Pieter C. M. M. Magusin, Ammonium Gallophosphates
Rutger A. van Santen,
Gopinathan Sankar, and
John Meurig Thomas
Scott R. Segal, Steven L. Suib,* 1687 Photoassisted Decomposition of Dimethyl Methylphosphonate over
Xia Tang, and Sunita Satyapal Amorphous Manganese Oxide Catalysts
Guillaume Clet,* 1696 Synthesis of a Zeolite Y Coating on Stainless Steel Support
Jacobus C. Jansen, and
Herman van Bekkum
Rafeh Bechara,* David Balloy, 1703 Influence of the Characteristics of (gamma)-Aluminas on the Dispersion and the
Jean-Yves Dauphin, and Reducibility of Supported Cobalt Catalysts
Jean Grimblot
Mikko Ritala,* Pia Kaisi, 1712 Controlled Growth of TaN, Ta(3)N(5), and Ta(x)N(y) Thin Films by Atomic
Diana Riihela, Kaupo Kukii, Layer Deposition
Markka Leskela, and Janne Jokinen
Ryo Tamaki and Yoshiki Chujo* 1719 Synthesis of Polystyrene and Silica Gel Polymer Hybrids Utilizing Ionic
Interactions
J. Yu, J. Li, K. Sugiyama, N. Togashi, 1727 Formation of a New Layered Aluminophosphate [Al(3)P(4)O(16)][C(5)N(2)H(9)](2)[NH(4)]
0. Terasaki,* K. Hiraga, B. Zhou,
S. Qiu, and R. Xu*
Elaine Nicolas-Tolentino, 1733 Effects of Cu(2+) Ions on the Structure and Reactivity ofTodorokite- and
Zheng-Rong Tian, Hua Zhou, Cryptomelane-Type Manganese Oxide Octahedral Molecular Sieves
Guanguang Xia, and Steven L. Suib*
V. Alexiev, 1742 Solid-State NMR Study ofHydrated Intercalation Compounds of
H. Meyer zu Altenschildesche, Molybdenum Disulfide
R. Prins, and Th. Weber*
W. K. Hsu, S. Trasobares, 1747 Electrolytic Formation of Carbon-Sheathed Mixed Sn-Pb Nanowires
H. Terrones, M. Terrones, N. Grobert,
Y. Q. Zhu, W. Z. Li, R. Escudero,
J. P. Hare, H. W. Kroto, and
D. R. M. Walton*
Aintzane Goni, Luis Lezama, 1752 Intercalation ofCu(2+) in the HNiPO(4).H(2)O Layered Phosphate: Study of
Jose Luis Pizarro, Jaione Escobal, the Structure, Spectroscopic, and Magnetic Properties of the Intercalated
Maria Isabel Arriortua, and Derivative and the Related CuNi2(P04)2 Compound
Teofilo Rojo*
P. A. Salvador, K, B. Greenwood, 1760 Substitution Behavior and Stable Charge Carrier Species in Long-Bond
J. R. Mawdsley, Length Layered Cuprates
K. R. Poeppelmeier,* and T. 0. Mason
Andrew M. Fogg and Dermot O'Hare* 1771 Study of the Intercalation of Lithium Salt in Gibbsite Using
Wonyoung Choe, Y.-H. Kiang, 1776 Coordination Networks of C(3v) and C(2v) Phenylacetylene Nitriles and
Zhengtao Xu, and Stephen Lee* • Silver(I) Salts: Interplay of Ligand Symmetry and Molecular Dipole
Moments in the Solid State
M. A. Diaz-Garcia, D. Wright, 1784 Photorefractive Properties of Poly(N-vinyl carbazole)-Based Composites for
J. D. Casperson, B. Smith, E. Glazer, High-Speed Applications
W. E. Moemer,*
L. 1. Sukhomlinova, and R. J. Twieg*
Louise S. Price, Ivan P. Parkin,* 1792 Atmospheric Pressure Chemical Vapor Deposition of Tin Sulfides (SnS,
Amanda M. E. Hardy, Sn(2)S(3), and SnS(2)) on Glass
Robin J. H. dark,
Thomas G. Hibbert, and
Kieran C. Molloy
G. Klarner, J.-L Lee, V. Y. Lee, 1800 Cross-linkable Polymers Based on Dialkylfluorenes
E. Chan, J.-P. Chen, A. Nelson,
D. Markiewicz, R. Siemens,
J. C. Scott, and R. D. Miller*
Chien-Chung Han,* Jyh-Tsung Lee, 1806 A New and Easy Method for Making Well-Organized Micrometer-Sized
Reen-Woei Yang, Hua Chang, and Carbon Tubes and Their Regularly Assembled Structures
Chein-Hwa Han
Jay J. Senkevich* and SeshlvB. Desu 1814 Near-Room-Temperature Thermal Chemical Vapor Deposition of
Poly(chloro-P-xylylene)/SiO(2) Nanocomposites
Stephen O'Brien, Robin J. Francis, 1822 Time-Resolved in Situ X-ray Powder Diffraction Study of the Formation of
Andrew Fogg, Dermot O'Hare, Mesoporous Silicates
Nanae Okazaki, and
Kazuyuki Kuroda
Ekkehard Lindner,. 1833 Sol-Gel Processed Phosphine Ligands with Two T- or D-Silyl
Wolfram Wielandt, Functionalities and Their (n(5)-C(5)Me(5))Ru(II) Complexes
Andreas Baumann,
Hermann A. Mayer, Ulrich Reinohl,
Achim Weber, Teja S. Ertel, and
Helmut Bertagnolli
Timo Hatanpää, Jarkko lhanus, 1846 Properties of[Mg(2)(thd)(4)] as a Precursor for Atomic Layer Deposition of
Jarno Kansikas, llpo Mutikainen, MgO Thin Films and Crystal Structures of [Mg2(thd)4] and
Mikko Ritala, and Markku Leskela* [Mg(thd)2(EtOH)2]
John D. Brennan,* 1853 Fluorescence and NMR Characterization and Biomolecule Entrapment
J. Stephen Hartman, Studies of Sol— Gel-Derived Organic—Inorganic Composite Materials
Elizabeth L llnicki, and Formed by Sonication of Precursors
Michael Rakic
A. Tuel 1865 Layered Intermediates in Zeolite Synthesis: Are Structures Related?
Kuei-Fang Hsu and Sue-Lein Wang* 1876 Extended Frameworks Encapsulating Facial {MoO3} Units: Syntheses
and Structural Characterizations of Ba3(MoO3)3(H2O)(AsC)4)2,
SrMoO(3)HAsO(4).H(2)O, and Sr(MoO(2)AsO(4))2
Wei Wang, Xiao Chen, and 1883 Fabrication of Semiconductor Nanoparticles in a Three-Dimensional
Shiomo Efrima* Organic-Layered Solid Crystal
V. Percec,* H. Oda, and A. D. Asandei 1890 Heterochiral Recognition in Molecular and Macromolecular Pairs of Liquid
Crystals Based on (R)- and (S)-2-Chloro-4-methylpentyl
4'-[[8-(Vinyloxy)octyl)oxy]biphenyl-4-carboxylate] Enantiomers
Jeffrey J. Thomas and 1907 Effects of D(2)O and Mixing on the Early Hydration Kinetics of Tricalcium
Hamlin M. Jennings* Silicate
S. Brasselet, F. Cherioux, 1915 New Octupolar Star-Shaped Strucures for Quadratic Nonlinear Optics
P. Audebert, and J. Zyss*
Kunpyo Hong, Young-Uk Kwon,* 1921 Syntheses and Magnetic Properties of Layered LnSrMno.5()O(4)(Ln=La
Duk-Kyun Han, Jeong-Soo Lee, and Pr, Nd, Sm, Gd) Compounds
Sung-Hyun Kim
M. Oledzka, N. E. Brese, and 1931 Hydrothermal Synthesis of BaTiO(3) on a Titanium-Loaded Polymer
R. E. Riman* Support
Time-Resolved in Situ X-ray Diffraction