SOLID STATE IONICS

Volume 122, Number 1-4, (July 1999)

Abstracted/Indexed in: Current Contents: Chemical and Earth Sciences/El Compendex Plus/INSPECi'Metals
Abstracts/Polymer Contents

CONTENTS

Structural consideration on the ionic conductivity of perovskite-type oxides
H. Hayashi, H. Inaba, M. Matsuyama, N.G. Lan, M. Dokiya and H. Tagawa 1

Model for anomalous transport of oxygen in nonstoichiometric perovskites. Analytical and numerical solutions

E. Goldberg, A. Nemudry, V. Boldyrev and R. Sch511hom 17
Lithium ion transport in Li(2)SO(4)-Li(2)O-P(2)O(5) glasses
M. Ganguli, M.H. Bhat and K.J. Rao 23 23

Electrochemical recovery and isotope separation of lithium ion employing lithium ion conductive perovskite-type
oxides
S. Kunugi, Y. Inaguma and M. ltoh 35

Oxygen tracer diffusion in undoped lanthanum manganites
A.V. Berenov, J.L. MacManus-Driscoll and J.A. Kilner 41

Relation between grain size and hydrogen diffusion coefficient in an industrial Pd-23% Ag alloy
S. Heinze, B.Vuillemin, J.-C. Colson, P. Giroux and D. Leterq 51

Anti-fluorite type Li(6)CoO(4) Li(5)FeO(4), and Li(6)MnO(4) as the cathode for lithium secondary batteries
S. Narukawa, Y. Takeda, M. Nishijima, N. Imanishi, 0. Yamamoto and M. Tabuchi 59

Diffusion mechanism and ion exchange equilibria of some heavy metal ions on cerium(IV) antimonate as cation
exchanger

I.M. EI-Naggar, E.S. Zakaria, S.A. Shady and H.F. Aly 65
Si-containing disordered carbons prepared by pyrolysis of pitch/polysilane blends: effect of oxygen and sulfur

D. Larcher, C. Mudalige, A.E. George, V. Porter, M. Gharghouri and J.R. Dah 71
Reaction mechanisms of Li(2.6)Coo(4)N anode material

T. Shodai, Y. Sakurai and T. Suzuki 85
Molecular dynamics simulation of gadolinia-doped ceria

H. Inaba, R. Sagawa.iH. Hayashi and K. Kawamura 95
TSDC relaxation map analysis in a Na-mordenite zeolite

S. Devautour, F. Henn, J.C. Giuntini, J.V. Zanchetta and J. Vanderschueren 105
Combustion synthesis and characterization of Sr and Ga doped LaFeO,
Q. Ming, M.D. Nersesyan, A. Wagner, J. Ritchie, J.T. Richardson, D. Luss, A.3. Jacobson and Y.L. Yang 113

________________________________________

SOLID STATE IONICS
Volume 120, no. 1-4 (May 1999)


CONTENTS


Electrochemical characteristics of the dimercaptan-poly(ethylene oxide) grafted polyaniline electrodes
H.-S. Moon and J.-K. Park 1


On the behavior of a dense indium oxide/yttria-stabilized zirconia electrode
D.I. Bronin, B.L. Kuzin, H. Nafe and F. Aldinger 13


Conductivity relaxation in zirconium fluoride glasses: effect of substitution of Zr(4+ ) by Y (3) ions
M. Sural and A. Ghosh 27

Densification and conductivity enhancement of Na(4) Zr(20 O(12) - abased solid electrolytes using TiO(2) as a sintering aid
T. Takeuchi, E. Betourne, D.C. Sinclair, M. Tabuchi, A.R. West and H. Kageyama 33



Morphology and protonic conductivity of the polyurethanes with acid groups in the flexible segment
VV. Shilov, VV. Shevchenko, P. Pissis, A. Kyritsis, Yu.P. Gornza, S.D. Nesin and N.S. Klimenko 43


Simultaneous doping with La(3+) and Y(3+) for Ba(2+)- and Ce(4+)-sites in BaCeO(3) and the ionic conduction
G. Ma, T. Shimura and H. Iwahara


Ionic conduction in Cu(x) Ag(1-x),BrTe solid solutions
A. Murakami, T. Sakuma, H. Takahashi, Y. Onoda and R.B. Beeken 61

]

Mixed electronic and ionic conductivity of LaCo( M ) O (3) (M = Ga, Cr, Fe or Ni).V. Oxygen permeability of Mg-doped
La(Ga, Co)O(3-8) perovskites
A.A. Yaremchenko, W. Kharton, A.P. Viskup, E.N. Naumovich, VN. Tikhonovich and N.M. Lapchuk 65



Electrochemical performance of mixed ionic-electronic conducting oxides as anodes for solid oxide fuel cell
S. Wang, Y. Jiang, Y. Zhang, W. Li, J. Van and Z. Lu 75



Electrical conducting properties of proton-conducting terbium-doped strontium cerate membrane
X. Qi and Y.S. Lin 85


Improvement of electrochemical properties of the spinel LiMn(2)O(4) using a Cr dopant effect
G.X. Wang, D.H. Bradhurst, H.K. Liu and S.X. Dou 95

The phase transition and optimal synthesis temperature of LiNiO(2)
Z. Lu, X. Huang, H. Huang, L. Chen and J. Schoonman 103

Lithium insertion into Li(4)V(3)O(8)
J. Kawakita, T. Miura and T. Kishi 109

Effects of nitrogen on the carbon anode of a lithium secondary battery
Y. Wu, S. Fang and Y. Jiang 117


Niobium based tetragonal tungsten bronzes as potential anodes for solid oxide fuel cells: synthesis and electrical
characterisation
P.R. Slater and J.T.S. Irvine 125


Impedance studies on polyacrylonitrile-CuX(2)-DMSO (X=CI, Br, CF(3) SO(3) solid polymer electrolyte
A. Lewandowski, 1. Stepniak and 1. Majchrzak 135


Chemical diffusivity of BaTiO(3-8) 1. Experimental determination
C.-R. Song and H.-l. Yoo 141


Electrochemical and structural properties of HT-LiCoO(2) and LT-LiCoO(2) prepared by the citrate sol-gel method
S.G. Kang, SY. Kang, K.S. Ryu and S.H. Chang 155


Electrochemical behaviour of oxygen at nickel nest cathodic material with catalyst La(1-x) Sr(x) CoO(3)
C.-F. Kao and C.-L. Zheng 163


Effect of Li(2)O doping on electrical properties of CoFe(2)O(4)
M. Soliman Selim, G. Turky, M.A. Shouman and G.A. EI-Shobaky 173


Synthesizing 0.9PZN-O.IBT by mechanically activating mixed oxides
X. Junmin, T. Yunling, W. Dongmei and J. Wang 183


Polymerization of aniline in the galleries of layered HNbMoO(6)
H.-J. Nam, H. Kirn, S.H. Chang, S.-G. Kang and S.-H. Byeon 189


The microscopic features of (Li(0.5)La(0.5) TiO(3)
H.-T. Chung and D.-S. Cheong 197


Preparation and structure of silicon doped tin oxide composites using an advanced ultrasonic spray method
H. Huang, E.M. Kelder, L. Chen and J. Schoonman 205


Reaction kinetics of the Pt, O(2) (g) c-ZrO(2) system: precursor-mediated adsorption
A. Mitterdorfer and L.J. Gauckler 211


Electrical properties ofLiCr(1-x) A1(x)TiO(4) (0 < x<0.4)
M.A. Arillo, M.L. Lopez, C. Pico and M.L. Veiga 227


Na (x/2) Bi( 1-x/2) Mo(x) V( 1-x) O(4) and Bi(1-x/3) Mo(x) V(1-x) New Scheelite-related phases
T. Duraisamy and A. Ramanan 233


Intercalation thermodynamics and chemical diffusion of oxygen in the solid solution YBa(2)Cu(3-x)_ Co,O(6+8)
E.B. Mitberg, M.V. Patrakeev, A.A. Lakhtin, I.A. Leonidov, V.L. Kozhevnikov and K.R. Poeppelmeier 239


Synthesis of the nanocrystalline (x-LiFe(50O(8) in a solvothermal process
B. Li, Y. Xie, H. Su, Y. Qian and X. Liu 251


Protonic conducting properties of sol-gel derived organic/inorganic nanocomposite membranes doped with acidic
functional molecules
1. Honma, Y. Takeda and J.M. Bae 255


Microstructure and electrical properties of YSZ-NiO composites
Y. M. Park and G. M. Choi 265


Studies on strontium substituted rare earth manganites
S.T. Aruna, M. Muthuraman and K.C. Patil 275


Oxygen permeability of La(2)Cu(Co)O(4+8) solid solutions
D.M. Bochkov.VV. Kharton, A.V. Kovalevsky, A.P.Viskup and E.N. Naumovich 281


Calendar 289

Author index 291


Subject index 295

__________________________________

SOLID STATE IONICS
VOL:119, NO:1-4, APRIL 1999

Sponsors and Organizing Committee vi
Preface vii
List of Participants x

Chapter 1. Mixed ionic-electronic conductors

Composition, structure and transport properties of perovskite-type oxides
H. Ullmann and N. Trofirnenko 1

Transition from ionic to electronic conduction in silver-vanadate-phosphate glasses
J.E. Garbarczyk, M. Wasiucionek, P. Machowski and W. Jakubowski 9

Diffusion transport in hexagonal ferrites with magnetoplumbite structure
V.M. Zhukovsky, O.V. Bushkova, V.M. Zainullina, G.I. Dontsov, L.I. Volosentseva and A.S.
Zhukovskaya 15

Transport properties of the LiNi1-yCoyO2 system
J. Molenda, P. Wilk and J. Marzec 19

Composition and conductivity of some nickelates
V.V.. Vashook, I.I. Yushkevich, L.V. Kokhanovsky, L.V. Makhnach, S.P. Tolochko, 1. F. Kononyuk, H.
Ullmann and H. Altenburg 23

X-ray study of the superionic phase transition in CU6PS5Br
A. Haznar, A. Pietraszko and 1.P. Studenyak 31

Chapter 2. Defects, reactions, diffusion

Doping of ionic compounds: solubility limit and self-compensation
Y. Tsur and 1. Riess 37

Transport properties of (Sn,Ti)02 polycrystalline ceramics and thin films
M. Radecka, P. Pasierb, K. Zakrzewska and M. Rekas 43

Solid state spreading and crystallisation of refractory oxides
A. Neiman and V. Utiurnov 49

Ambipolar Diffusion in TiO2,
M. Radecka, P. Sobas and M. Rekas 55

Electrical and electrochemical properties of Bi,Sr,CaCu208+gama superconductor
J. Molenda, 1. Nowak, M. Paleczny and J. Marzec 61

Electrosurface transfer in the CaWO4-WO3, system
A. Neiman and E. Konisheva 75

Chapter 3. Experimental methods

EXAFS studies of the cation sites in BIMEVOX fast-ion conductors
A.V. Chadwick, C. Colli, C. Maltese, G. Morrison, 1. Abrahams and A. Bush 79

Structural and electrical properties of double-layer ceria/yttria stabilized zirconia deposited on silicon
substrate
M. Hartmanova, K. Gmucova, M. Jergel, 1. Thurzo, F. Kundracik and M. Brunel 85

Voltammetric measurements on Me ,0, (Me = Bi, Cu, V) compounds and comparison with results for
BICUVOX.IO
G. Fafilek and S. Harasek 91

Ionic transport in porous polypyrrole films: piezoelectric microgravimertry studies
A. Lisowska-Oleksiak and T. Zaiewska 97

Optical investigations of superionic phase transition in Ag2CdI4 thin films
I.M. Bolesta, 0V. Futey and O.G. Syrbu 103

Dynamic current-voltage characteristics of ionically conducting solids
H. Sodolski and M. Koziowski 109

Study of grain boundary polarization by two-probe and four-probe impedance spectroscopy
J.R. Dygas, G. Fafilek and M.W. Breiter 115

Chapter 4. Inorganic conductors

Oxygen exchange behaviour and electrical conductivity of polycrystalline oxide-ion conductors based on
Ce1-nLanO2-0.5n
H.-J. Lang, K. Kiinstler and G. Tomandi 127

Inelastic neutron scattering study of the superionic solid solutions Ba1-xLax.F2+x
F. Kadlec, F. Moussa, P. Simon and B.P. Sobolev 131

Electrical conductivity and structure correlation in BIZNVOX
F. Krok, 1. Abrahams, A. Zadrozna, M. Malys, W. Bogusz, J.A.G. Nelstrop and A.J. Bush 139

Relaxation dispersion of ionic conductivity of BICOVOX
A. Kezionis, W. Bogusz, F. Krok, J. Dygas, A. Orliukas, 1. Abrahams and W. Gebicki 145

Comparative two- and four-probe impedance measurements on BICUVOX.1O
P. Kurek and G. Fafilek 151

Li+-ion conductivity of BPO4-Li2O; the relation between crystal structure and ionic conductivity
M.J.G. Jak, E.M. Kelder, Z.A. Kaszkur, J. Pielaszek and J. Schoonman 159

Particular features of admittance spectra of polycrystalline NASICON samples
W. Bogusz, F. Krok and W. Piszczatowski 165

Microstructure and physical properties of superionic eutectic composites of the LiF-RF3 (R = rare earth
element) system
V. Trnovcova, P.P. Fedorov, C. Barta, V. Labas, V.A. Meleshina and B.P. Sobolev 173

Fast ionic conductivity of PbF2:MF2 (M=Mg, Ba, Cd) and PbF2:ScF3 single crystals and composites
V. Trnovcova, P.P. Fedorov, I.I. Buchinskaya,V. Smatko and F. Hanic 181

Chapter 5. Interfaces, electrodes

Defect chemistry and chemical transport involving interfaces
J. Jamnik and J. Maier 191

Impedance of the Na+ solid electrolyte/perovskite electrode interface in an 02-containing atmosphere
N.G. Bukun, N.S. Tkacheva and L.S. Leonova 199

The interface between lithium and poly(ethylene-oxide)
A. Lisowska-Oleksiak 205

Chapter 6. Gels, glasses, polymers

Lithium conduction in inorganic gel monoliths containing LiNO3 or LIBr at low temperatures
M. Wasiucionek and M.W. Breiter 211

Fast ionic transport in solid polymer electrolytes based on acrylonitrile copolymers
O.V. Bushkova,V.M. Zhukovsky, B.I. Lirova and A.L. Kruglyashov 217

Spectrofluorimetric studies of lithium conducting silica gels with LiNO3, LiCI or LiBr
M. Wasiucionek and M.W. Breiter 223

Studies of silver-vanadate superionic glasses using Raman spectroscopy
R. Lewandowska, K. Krasowski, R. Bacewicz and J.E. Garbarczyk 229

Glasses and supercooled melts in the Li2O-P2O5 system
G.B. Pakhornov and S.L. Neverov 235

Diffusion behaviour of 22Na in the poly(ethylene oxide)-poly(vinyl acetate) system
I.E. Animitsa, L.I. Volosentseva and V.M. Zhukovsky 245

Gel polyelectrolytes based on lithium carboxylates
Z. Florjanczyk,W. Bzducha, J.R. Dygas, B. Misztal-Faraj and F. Krok 251

Chapter 7. Proton conductors

Neutron scattering in proton conducting perovskite-oxides
I.M. Sosnowska 261

Proton conducting polymer composites for electrochromic devices
G. Vaivars, A. Azens and C.G. Granqvist 269

Low-temperature proton conductivity in hydrated and nonhydrated tin dioxide
Yu. Dobrovolsky, L. Leonova, S. Nadkhina and N. Panina 275

Structural aspects of fast proton transport in (NH4)3H(SeO4)2 single crystals
A. Pietraszko, B. Hilczer and A. Pawlowski 281

Proton conducting polymer gel electrolytes
G. Zukowska, M. Rogowska, E. Weczkowska and W. Wieczorek 289

Effect of Si02 morphology and pores size on the proton nanocomposite electrolytes properties
V.G. Ponomareva, G.V. Lavrova and L.G. Simonova 295

Chapter 8. Miscellaneous

Novel proton conducting composite electrolytes for application in methanoi fuel cells
Z. Poltarzewski, W. Wieczorek, J. Przyluski and V. Antonucci 301

Fast ionic conducting film ceramic membranes with advanced applications
B. Zhu 305

Thermodynamic properties of some perovskite type oxides used as SOFC cathode materials
S. Tanasescu, N.D. Totir and D.I. Marchidan 311

Chemical spray deposition of YSZ and GCO solid electrolyte films
P. Bohac and L. Gauckler 317

Spatio-temporal coupling in the continuous-time Levy flights
R. Kutner 323

Diffusion coefficients of an interacting lattice gas beyond the quasichemical approximation
S. Bokun, C. Uebing, V.S. Vikhrenko and V.A. Zhuk 331

Fluctuation theory of low and high frequency Jonscher-type response of disordered ionic conductor
V.N. Bondarev and P.V. Pikhitsa 337

Author index 345
Subject index 349

____________________________________________________
SOLID STATE IONICS
Volume 118, numbers 3-4 , March 1999



CONTENTS


The high temperature proton conductor Ba(3) Ca( 1.82 ) O ( 9-8) . Part II: electrochemical cell measurements
and TEM,
T. Schober, H.G. Bohn, T. Mono and W. Schilling 173


Use of Li-M-Mn-O [M = Co, Cr, Ti] spinels prepared by a sol-gel method as cathodes in high-voltage
lithium batteries
L. Heman, J. Morales, L. Sanchez and J. Santos 179


Ln( 1-x ) Sr(x) MnO(3) (Ln=Pr, Nd, Sm and Gd) as the cathode material for solid oxide fuel cells
Y. Sakaki, Y. Takeda, A. Kato, N. Imanishi, 0. Yamamoto, M. Hattori, M. lio and Y. Esaki 187



Structural and spectroelectrochemical investigations of tetragonal CeVO(4) and Ce/V-oxide sol-gel derived
ion-storage films
U. Opara Krasovec, B. Orel, A. Surca, N. Bukovec and R. Reisfeld 195


Transition metal doped lanthanum gallates
N. Trofirnenko and H. Ullmann 215


Ionic and electronic conduction in La(0.95) Sr(0.05) GaO(3-8) La(0.95) Sr(0.05) AlO(3-8) and Y(0.95)Sr(0.05) Alo(3-8)
P.S. Anderson, F.M.B. Marques, D.C.Sinclair and A.R.West 229


Electronic conductivity in the Pr(1-x) Sr (x)Co(1-y)Mn(y)O(3) system
G.Ch. Kostogloudis, P. Fertis and Ch. Ftikos 241



The formation of Na-beta-gallate in the Na(2)O . Ga(2)O(3) -Ga(2)O(3) system
C.K. Kuo and P.S. Nicholson 251


Creep behavior of doped lanthanum gallate versus cubic zirconia
J. Wolfenstine, P. Huang and A. Petric 257


NIR-Raman studies of poly(ethylene oxide) + (NH4) (4) H(2) SeO4(3) polymer electrolyte
M. Polomska, J. Wolak, B. Hilczer and L. Szczepanska 261






Raman studies of LaGaO(3) and doped LaGaO(3)
T. Inagaki, K. Miura, H. Yoshida, J. Fujita and M. Nishimura 265



Grain size-dependent electrical properties of rutile (TiO2)
C. Demetry and X. Shi 271


Effect of multi-stage dehydration on electrical conductivity of zeolite A
P. Qiu, Y. Huang, R.A. Secco and P.S. Balog 281


Proton conduction in acid doped polybenzimidazole
R. Bouchet and E. Siebert 287


Dynamic mechanical spectroscopy and conductivity studies of gel electrolytes based on stereocornplexed
poly(methyl methacrylate)
Y.K. Yarovoy, H.P. Wang and S.L. Wunder 301


Proton mobility in H-ZSM5 studied by impedance spectroscopy
M.E. Franke and U. Simon 311


The influence of heterogeneous dopant porous structure on the properties of protonic solid electrolyte in
the CsHSO(4)-SiO(2) system
V.G. Ponomareva, G.V. Lavrova and L.G. Simonova 317


Trivalent ion conduction of the Sc(2)(WO4) -Lu(2)(WO4(3) system
Y. Kobayashi, T. Egawa, S. Tamura, N. Imanaka and G. Adachi 325


Enhanced specific grain boundary conductivity in nanocrystalline Y(2)O(3)-stabilized zirconia
P. Mondal, A. Klein, W. Jaegermann and H. Hahn 331


Relaxation of sodium ions in sodium diborate glass
A. Doi 341


Molecular dynamics study on lattice vibration and heat capacity of yttria-stabilized zirconia
T. Tojo, H. Kawaji and T. Atake 349


Defect, protons and conductivity in brownmillerite-structured Ba(2)ln(2)O(5)
C.AJ. Fisher and M.S. Islam 355


Calendar 365

Author index 367

Subject index 371
_______________________

_____________________________

SOLID STATE IONICS

VOL. 123, NO. 1-4, August 1999

Abstracted/Indexed in: Current Contents: Chemical and Earth Sciences/El Compendex PluslINSPECI Metals
Abstracts I Polymer Contents

CONTENTS

Apparent oxygen solubility in refractory carbides
D. Gozzi, M. Montozzi and P.L. Cignini 1

Oxidation kinetics of refractory carbides at low oxygen partial pressures

D. Gozzi, M. Montozzi and P.L. Cignini 11
Brightness degradation in electroluminescent ZnS:Cu

N.E. Brese, C. L. Rohrer and G.S. Rohrer 19
Synthesis and characterization of non-stoichiometric nickel-copper manganites

C. Drouet, P. Alphonse and A. Rousset 25
Synthesis of nanocrystalline Mn-oxides by gas condensation
L. Dimesso, L. Heider and H. Hahn 39

Phase diagram study in the CaO-Cr2O3-La2O3 system in air and under low oxygen pressure
D.H. Peck, M. Miller and K. Hilpert 47

Phase diagram studies in the SrO-Cr2O3-La2C3 system in air and under low oxygen pressure
D.H. Peck, M. Miller and K. Hilpert 59

Raman study of the phase transitions sequence in pure WO3 at high temperature and in HxWO3 with variable
hydrogen content
E. Cazzanelli, C. Vinegoni, G. Mariotto, A. Kuzmin and J. Purans 67

Demixing of mixed oxide (A,B)0 in an oxygen potential gradient: numerical solution of the time evolution of the

demixing process

J.-O. Hong, 0. Teller, M. Martin and H.-L Yoo 75
The effect of mineralizers on the crystallization of zirconia gel under hydrothermal conditions

G. DelVAgli, A. Colantuono and G. Mascolo 87
Synthesis of LiCoO2 particles with uniform size distribution using hydrothermally precipitated Co3O4 fine particles

T. Nakamura and A. Kajiyama 95
Sintering behavior and mechanism of Sr-doped lanthanum chromites with A site excess composition in air

M. Mori, Y. Hiei and N.M. Sammes 103
Reaction mechanism between lanthanum manganite and yttria doped cubic zirconia

M. Mori, T. Abe, H. ltoh, 0. Yamamoto, G.Q. Shen, Y. Takeda and N. Imanishi 113
Atomistic simulation of defects and ion migration in LaYOg

E. Ruiz-Trejo, M.S. Islam and J.A. Kilner 121



Gd1_xAxCo1_yMny03 (A = Sr, Ca) as a cathode for the SOFC
M.B. Phillipps, N.M. Sammes and 0. Yamamoto 131

Synthesis and electrochemical properties of cobalt vanadates vs. lithium
E. Baudrin, S. Laruelle, S. Denis, M. Touboul and J.-M. Tarascon 139

Electrical properties of LiMn^O^g at temperatures 220-IIOOK
J. Molenda, K. Swierczek, W. Kucza, J. Marzec and A. Stoklosa 155

Diffusion coefficient measurement of lithium ion in sintered li (1.33)Ti(1.67)O(4) by means of neutron radiography
S. Takai, M. Kamata, S. Fujine, K. Yoneda, K. Kanda and T. Esaka 165

Lithium location in NASICON-type Li+ conduclois by neutron diffraction. 1. Triclinic a- Lizr2(po4)3
M. Catti, S. Stramare and R. lbberson 173

Preparation and lithium insertion behaviour of Sr" substituted a -SryAgo(75-2y)V2O5

J. Kawakita, R. Shimizu, Y. Katayama, T. Mini a and T. Kishi 181

Anodes based on oxide materials for lithium rechaigeable batteries
H. Li, X. Huang and L. Chen 189

A solid oxide fuel cell with a gadolinia-doped ceria anode: preparation and performance
O.A. Marina, C. Bagger, S. Prirndahl and M. Mogensen 199

An electrode kinetics study of H2 oxidation on Ni/Y2O3-ZrO2 cermet electrode of the solid oxide fuel cell
S.P. Jiang and S.P.S. Badwal 209

The ionicity of binary oxides and silicates
Y.Y. Guo, C.K. Kuo and P.S. Nicholson 225

Novel single ion, comb-branched polymer electrolytes
J.M.G. Cowie and G.H. Spence 233

Electrochemical performance of lithium-ion polymer cell using gel polymer electrolyte based on acrylonitrile-methyl
methacrylate-styrene terpolymer
D.-W. Kirn, B.-K. Oh and Y.-M. Choi 243

Polymer electrolytes prepared by polymerizing mixtures of polymerizable PEO-oligomers, copolymer of PVDC and
poly(acrylonitrile), and lithium triflate
C. Kirn, G. Lee, K. Liou, K.S. Ryu, S.-G. Kang and S.H. Chang 251


Ionic conductivity ofAgx(GeSe3)1_x (0(<or=)x(<or=) 0.571) glasses
M. Kawasaki, J. Kawamura, Y. Nakamura and M. Aniya 259

Ionic conductivity studies of ultrafine-grained yttria stabilized zirconia polymorphs
R. Ramarnoorthy, D. Sundararaman and S. Ramasamy 271

Electrical conductivity of the systems, (Y1-xMxNbO7 (M = Ca, Mg) and Y3Nb1-xMxO7 (M' == Zr and Ce)

H. Yamamura, K. Matsui, K. Kakinuma and T. Mori 279

The influence of preparation conditions on the electrical conductivity of poly-N-methylpyrrole films
K.P. Vidanapathirana, M.A. Careem, S. Skaarup and K. West 287

Formation of SrVC)3 precursors from Sr(OH)2 and V(111)0(11)(2/5 (<or=)m/n (<or =) 2/3) by mechanical stressing under ambient
or reducing atmosphere
W.-S. Lee, T. Isobe and M. Senna 293

Sintering of zirconia-yttria ceramics studied by impedance spectroscopy
D.Z. de Florio and R. Muccillo 301

Synthesis and characterization of perovskite catalysts
J. Kirchnerova and D. Klvana 307

A novel one-step solvothermal route to nanocrystalline CuSbS2 and Ag3SbS3
H. Su, Y. Xie, S. Wan, B.Li and Y. Qian 319

EPR of gamma irradiated ammonium and caesium formates
F. Koksal, 0. Karamustafaoglu and B. Karabulut 325

Calendar 329

Author index 331

Subject index 335

____________________________

SOLID STATE IONICS
Volume 116, numbers 1-2, January 1999

CONTENTS

Electronic structure and electrochemical properties of electrode material Li(7-x)-MnN(4)
S. Suzuki and T. Shodai 1

Lithium-ion conductivity in the novel Lai(1/3-x)Li(3x)NbO(3) solid solution with perovskite-related structure
S. Garcfa-Martfn, J.M. Rojo, H. Tsukamoto, E. Moran and M.A. Alario-Franco 11

Lithium/vacancy ordering in the monoclinic Li(x)NiO(2) (0.50 <x< 0.75) solid solution
J.R Peres, F. Weill and C. Delmas 19

Chemical stability study of Li(2)SO(4) on the operation condition of a H(2)/O(2) fuel cell
S. Tao, Z. Zhan, R Wang and G. Meng 29

Aggregation of the doping salt in B(2)S(3)-Li(2)S-Lil glasses, effect on the dynamical properties
R Vinatier, M. Menetrier and A. Levasseur 35

Effects of alumina dispersion on ionic conduction of toughened zirconia base composite
A. Yuzaki and A. Kishimoto 47

Study on the ionic conductivity of polyether network polymer electrolytes: effect of the preparation
method
C.-H. Kirn, J.-K. Park and W.-J. Kirn 53

Ionic conductivity of polymer electrolytes based on phosphate and polyether copolymers
S.H. Kirn, J.Y. Kirn, H.S. Kirn and H.N. Cho 63

Ionic conductivity of pure sodium pyrophosphate Na(4)P(2)O(7)
S. Villain, E. Nigrelli and G. Nihoul 73

Electrical conductivity of iron-doped calcium titanate
L.A. Dunyushkina, A.K. Demin and B V. Zhuraviev 85
lectronic structures of hydrogen in perovskite-type oxide, SrTiO(3)
H. Yukawa, K. Nakatsuka and M. Morinaga 89

Automatic regulation of hydrogen partial pressure using a proton conducting ceramic based on SrCeC)3
H. Matsumoto, T. Suzuki and H. Iwahara 99

New counter electrode prepared as vanadium oxide and V/Ce oxide films: preparation and characterization
Z. Cmjak Orel 105

Structural characterization of partially amorphous Sn0(2) nanoparticles by factor analysis of XAS and
FT-IR spectra
V.M. Jimenez, A. Caballero, A. Femandez, J.P. Espinos, M. Ocana and A.R. GonzaIez-Elipe 117

Phase relations in oxygen-deficient SrCoO(2.5-delta)
W. Vashook, M.V Zinkevich and Yu.G. Zonov 129

Single crystal growth of YBa(2)Cu(3)O(7-delta) through a Pt compound intermediate phase
L. Morales, G. Polla, D.Vega, H. Lanza, P. Levy and G. Leyva 139

H(2) oxidation on Ni/Y-TZP cermet electrodes - polarisation behaviour
S.P. Jiang and Y. Ramprakash 145

Anionic conductivity and thermal stability of single crystals of solid solutions based on calcium fluoride
N.I. Sorokin and M.W. Breiter 157

A correlation between the change of the chemical potential of ionic and electronic defects and the phase
stability range as exemplified by solid solutions of manganese in iron oxide (Fe1_x ,Mn (x) )1-y O
A. Stoklosa, J. Zajecki and T.S. Wiltowski 167

___________________________

SOLID STATE IONICS

Volume 116, numbers 3,4 (January II 1999)

Abstracted/Indexed in: Current Contents: Chemical and Earth Sciences/El Compendex Plus/INSPEC/ Metals
Abstracts/Polymer Contents

CONTENTS

Electrochemical blackening of yttria-stabilized zirconia - morphological instability of the moving reaction
front
J. Janek and C. Korte 181


Synthesis and characterization of novel urethane cross-linked ormolytes for solid-state lithium batteries
V. de Zea Bermudez, L. Alcacer, J.L. Acosta and E. Morales 197


Structural transformation of the oxygen and proton conductor Ba2ln2O5 in humid air: an in-situ X-ray
powder diffraction study
W. Fischer, G. Reck and T. Schober 211

Hydrothermal synthesis and properties of mixed conductors based on Ce(1-x)PrxO(2.a) solid solutions
P. Shuk and M. Greenblatt 217


Thermophoresis-assisted vapour phase synthesis of CeO2 and CexY(1-x)O(2-a) nanoparticles
W. Bai, K.L. Choy, N.H.J. Stelzer and J. Schoonman 225

Ionic conductivity properties and (19)F NMR investigation of Pb(1-x)CrxF(2+x) solid solutions with fluorite-
type structure
M. El Omari, J. Senegas and J.-M. Reau 229


Application of mechanochemical treatment to the synthesis of A- and G-forms of La2Si2O7
G. Tzvetkov and N. Minkova 241

Kinetics of lithium intercalation into carbon anodes: in situ impedance investigation of thickness and
potential dependence
E. Barsoukov, J.H. Kirn, J.H. Kirn, C.O. Yoon and H. Lee 249

Lithium ion conduction in A-site deficient perovskites R)(1/4)Li(1/4)/TaC)3 (R==La, Nd, Sm and Y)
K. Mizurnoto and S. Hayashi 263

LiAIgNi(1-a)O2 solid solutions as cathodic materials for rechargeable lithium batteries
G.X. Wang, S. Zhong, D.H. Bradhurst, S.X. Dou and H.K. Liu 271

V2O5 aerogel-like lithium intercalation host
F. Coustier, J.-M. Lee, S. Passerini and W.H. Smyrl 279

Pseudo-equilibrium phase diagrams for PEO-Zn salts-based electrolytes
M.J.C. Plancha, C.M. Rangel and C.A.C. Sequeira 293

State of water in sulfonated poly(vinyl fluoride) membranes: an FTIR study
D. Ostrovskii, M. Paronen, F. Sundholm and L.M. Torell 301

Temperature effects on copper diffusion in natural chalcocite
Th. Pauporte and J. Vedel 311

Structure and proton conduction in CsDSO4
P. Zetterstr5m, A.V. Belushkin, R.L. McGreevy and L.A. Shuvalov 321

Ionic conductivity of gadolinium-doped barium praseodymium oxide
T. Fukui, S. Ohara and S. Kawatsu 331

Defect cluster formation in M2O3-doped CeO2
L. Minervini, M.O. Zacate and R.W. Grimes 339

Calendar 351

Author index 353

Subject index 357

__________________________

SOLID STATE IONICS

Volume 117, numbers 1,2 (February 1 1999)

Abstracted/Indexed in: Current Contents: Chemical and Earth Sciences/El Compendex Plus/INSPECI Metals
Abstracts/Polymer Contents

CONTENTS
Foreword 1
Obituaries 3

Grain boundary diffusion and oxidation processes
J. Philibert 7

Microscopy (AFM, TEM, SEM) studies of oxide scale formation on FeCrAI based ODS alloys
A. Czyrska-Filemonowicz, K. Szot, A. Wasilkowska.A. Gil and WJ. Quadakkers 13

Electrical conductivity of 0203 doped with Ti02
A. Holt and P. Kofstad 21

Experimental procedure for the determination of diffusion coefficients in ionic compounds - Application
to yttrium-doped zirconia
G. Petot-Ervas and C. Petot 27

Transport properties of LiMn2O4
J. Molenda and W. Kucza 41

Re-examination of the non-stoichiometry and defect structure of copper(ll) oxide or tenorite, Cu(1+-z) 0 or
Cu0i^. A short review
C. Carel, M. Mouallem-Bahout and J. Gaude 47

Transport properties and reactivity of tungsten trioxide
J. Molenda and A. Kubik 57


Defect structure model and transport properties of nonstoichiometric manganous sulphide
S. Mrowec, M. Danielewski and J. Gilewicz-Wolter 65

Transport properties and percolation in two-phase composites
J.R. Gavarri, L. Tortet and J. Musso 75

Application of metal oxidation and oxide reduction to determine superficial phases containing active
centres in redox catalysts
R. Dziembaj, J. Lojewska and T. Lojewski 87

Wustite phase transformations in iron catalysts for ammonia synthesis
A. Pattek-Janczyk, J.-C. Grenier and B. Miczko 95

Application of the static concentration waves theory to structural transitions in some oxides
G. Nihoul, Ch. Leroux, V. Madigou and J. Durak 105

An XRD and ESR study of V2O5/ZrO2 catalysts: influence of the phase transitions of Zr02 on the
migration of V(4+) ions into zirconia
A. Adamski, Z. Sojka, K. Dyrek and M. Che 113

On the usefulness of Campbell's concept of the rate-determining step
A. Baranski 123

Effect of reduction conditions on structure and phase composition of blast furnace charge composed of
alkaline sinters and acidic pellets
S. Jasienska, J. Orewczyk, A. Ledzki and J. Durak 129


Kinetics of the reduction of wustite of different compositions
D.I. Ryzhonkov and S.B. Sorin 145

The spinel phases LiAIy.Mn(2-x)04 (y==0, 1/12, 1/9, 1/6, l/3)and Li(AI,M),(1/6)Mn,(11/6)0(4) (M-Cr,Co)as
the cathode for rechargeable lithium batteries
D. Song, H. Jkuta, T. Uchida and M. Wakihara 151

Diffusion-controlled work function changes of (La,Sr)MnO3
T. Bak, J. Nowotny, M. Rekas and C.C. Sorrell 157


A comparative study of the surface and bulk properties of lanthanum-strontium-manganese oxides
La,_^Sr^MnO^^^ as a function ofSr-content, oxygen potential and temperature
P. Decorse, G. Caboche and L.-C. Dufour 161


Effect of segregation on the formation of interface structures. Example of Cr-Doped CoO
A. Bernasik, K. Kowalski and J. Nowotny 171


XPS and EELS investigations of chemical homogeneity in nanometer scaled Ti-ferrites obtained by soft
chemistry
P. Perriat, E. Erics, N. Millot and B. Domenichini 175

Calendar 185
_______________________________

SOLID STATE IONICS

Volume 117, numbers 3,4, (February 1999

Abstracted/Indexed in: Current Contents: Chemical and Earth Sciences/El Compendex Plus irNSPECI Metals
Abstracts/Polymer Contents

CONTENTS

Identification of the reaction mechanism of the Pt, O2(g)1yttria-stabilized zirconia system Part 1: General
framework, modelling, and structural investigation
A. Mitterdorfer and L.J. Gauckler 187

Identification of the reaction mechanism of the Pt, O2(g)1yttria-stabilized zirconia system Part II: Model
implementation, parameter estimation, and validation
A. Mitterdorfer and L.J. Gauckler 203

The high temperature proton conductor Ba3Ca(1.18)NB(1.82)O(9-a) Electrical conductivity
H.G. Bohn, T. Schober, T. Mono and W. Schilling 219

Electronic conductivity of Gd-doped ceria with additional Pr-doping
S. Lubke and H.-D. Wiemhofer 229

NMR studies of the lithium dynamics in two thioborate superionic conductors: Li9B19S33 and
li(4-2x)Sr(2+x)B10S19 (x-0.27)
R. Bertermann, W. Muller-Warmuth, C. Jansen, F. Hiltmann and B. Krebs 245

Synthesis and characterization of layer structured solid solutions in the system of LiCoO2-Li2MnO3
K. Numata, C. Sakaki and S. Yamanaka 257

Mixed conduction for the spinel type (I -x)Li(4/3)Ti(5/3)O(4-x)LiCrTiO4 system
M. Nakayama, Y. Ishida, H. lkuta and M. Wakihara 265

Lithium iron sulfide as an electrode material in a solid state lithium battery
K. Takada, K. lwarnoto and S. Kondo 273

Ln(0.4)Sr(0.6)CO(o.8)Fe(o. 2)O(3-a) (Ln=La, Pr, Nd, Sm, Gd) for the electrode in solid oxide fuel cells
H.Y. Tu, Y. Takeda, N. Imanishi and 0. Yamamoto 277

Selective detection of NO by using an amperometric sensor based on stabilized zirconia and oxide
electrode
N. Miura, G. Lu, M. One and N. Yamazoe 283


Phase stability of bismuth lead antimony oxide
Y. Du, N.M. Sammes, G.A, Tompsett and Y. Zhang 291

Synthesis and characterisation of rare earth substituted bismuth vanadate solid electrolytes
C.K. Lee and C.S. Ong 301

Thermal behavior of deuterium implanted into SrCe(0.95)YbO(3-a)
B. Tsuchiya, K. Soda, J. Yuhara, K. Morita and H. lwahara 311

Enhancement in conductivity for porous alumina-based Agl-AI2O3 composites by use of temperature and
concentration gradient
M. Nagai and T. Nishino 317


High-temperature deformation ofEaCe(1-x)Y(x)O(3-y) (0.05<or=0.2)
E.T. Park, K.C. Goretta, A.R. de Arellano-Lopez, J. Guan, U. Balachandran, S.E. Dorris and J.L.
Routbort 323


Low temperature synthesis of nanocrystalline Mn3O4 by a solvothermal method
Z. Weixin, W. Cheng, Z. Xiaoming, X. Yi and Q. Yitai 331

Ferroelectric and electric properties of Rb(0.6)(NH4)(0.4)HSO4 single crystal
H. Khemakhem, T. Mhiri and A. Daoud 337

Calendar 345
Author index 347
Subject index 351

___________________________

SOLID STATE IONICS

Volume 124, numbers 3,4 ,September 1999)

CONTENTS

Solubility range and ionic conductivity of large trivalent ion doped Na(1+x)MxZr(2-x)P3O12 (M: ln,Yb, Er,Y,
Dy, Tb, Gd) solid electrolytes
Y. Miyajima, T. Miyoshi, J. Tamaki, M. Matsuoka, Y. Yamamoto, C. Masquelier, M. Tabuchi, Y.Saito
and H. Kageyama 201


NMR studies of modified nasicon-like, lithium conducting solid electrolytes
M. Forsyth, S. Wong, K.M. Nairn, A.S. Best, P.J. Newman and D.R. MacFarlane 213


Statistical geometry of reaction space in porous cermet anodes based on ion-conducting electrolytes.
Patterns of degradation
A. loselevich, A.A. Kornyshev and W. Lehnert 221


Polymer-ceramic composite electrolytes: conductivity and thermal history effects
B. Kumar and L.G. Scanlon 239


Electric conductivity and dielectric permittivity of mixed electronic-ionic conductivity compounds
(BS)(1+x)(DAsS2)x (B = Ge, Pb; D - Ag, Cu)

E.R. Baranova,V.L. Kobelev, O.L. Kobeleva, N.V. Melnikova,V.B. Zlokazov, L.Ya. Kobelev and M.V.
Perfiliev 255


Co-doped LSGM: composition-structure-conductivity relations
N. Trofirnenko and.H. Ullmann 263


Mechanochemical fabrication of single phase PMN of perovskite structure
J. Wang, X. Junmin, W. Dongmei and N. Weibeng 271


An investigation of La Ni(1-x)FexO3 as a cathode material for solid oxide fuel cells
R. Chiba, F. Yoshimura and Y. Sakurai 281


Chemical diffusivity of BaTi(3-a) III. Conductivity-nonstoichiometry (8) correlation in a mixed n/p
regime
C.-R. Song and H.-I. Yoo 289


Calcium tracer diffusion in (La,Ca)CrC)3 by SIMS
T. Horita, M. Ishikawa, K. Yamaji, N. Sakai, H. Yokokawa and M. Dokiya 301


Humidity determination by solid state limiting current sensor
C.M. Man and G. Rabotti 309


Benzene-thermal co-reduction reaction for nanocrystalline intermetallics Fe3Si and Ni3AI
Q. Lu, J. Hu, K. Tang, Y. Qian, G. Zhou and X. Liu 317


High ionic conductivity of PEO/sulfonamide salt hybrids
Y. Tominaga and H. Ohno 323

Calendar 331

Author index 333

Subject index 335